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Holy Saturday is a pretty big deal in the Catholic Church.
I have to wonder: Would a "practicing Jew" accept a wedding invitation when the wedding day falls on Rosh Hashana?
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In situations like this, I like to think about what the Apostles would have done.
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For example, can you think of any one of the holy Apostles who would have attended a wedding the day after Good Friday?
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Furthermore, if one of them had been invited to such a wedding, perhaps his absence would speak louder than anything he could have said.
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St. Francis of Assisi believed that wearing the habit of his Order was a silent sermon.
He said in regards to Franciscans wearing their cassock, "Preach always, and if necessary, use words."
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If I were to go to a wedding on Holy Saturday, I would sit in the back, and not stand up or clap or anything like that, and I would respectfully give my "regrets" in advance to not attend the reception. A Catholic "celebrating" or making merry on that day would be scandalous. And if you can't make merry on a particular day, it's not right to attend a wedding party.
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If they really wanted YOUR attendance they would have avoided putting you in the position of having to make this choice, by choosing a different day, such as one during the Church's wedding ceremony times. There are certain times of the year when Catholics are forbidden from having weddings and this is one of them.
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