Thank you for your replies.
IIRC I've heard from Fr. Bitzer in one of his sermons that one should not bless oneself on the way out of Holy Mass. His reasoning was that every gesture in Church and during the Sacred Liturgy must be deliberate and with a definite purpose. Since the purpose of blessing oneself is to purify oneself for Mass and the Mass itself should erase venial sins given the right dispositions, it doesn't make sense to bless oneself after Mass. Something along those lines.
About what Twice Dyed posted: Would throwing away the fountain water on Holy Friday also apply to the faithful's supply for private use?